文献类型：期刊文献

英文题名：Direct C-arylation of polyfluoroarenes with diaryliodonium salts via Pd(OAc)2-catalysis

作者：Guo, Fenglou[1,2];Han, Jianwei[3];Mao, Song[1,2];Li, Juan[1,2];Geng, Xu[1,2];Yu, Jianjun[1,2];Wang, Limin[1,2]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200237, Peoples R China

年份：2013

卷号：3

期号：18

起止页码：6267

外文期刊名：RSC ADVANCES

收录：;EI(收录号：20132216372510);WOS:【SCI-EXPANDED(收录号:WOS:000317584200004)】；

基金：The work was supported by the National Nature Science Foundation of China (NSFC, 21272069, 20672035) and the Fundamental Research Funds for the Central Universities. We thank the Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry and The Chinese Academy of Sciences for their support.

语种：英文

外文关键词：Salts - Catalysis

摘要：A novel approach towards the Pd-catalyzed arylation of electron-deficient polyfluoroarenes with diaryliodonium salts was developed. The desired fluorinated biaryls were synthesized in good yields. The mechanistic insights involving the Pd-II/IV catalytic cycle for the present reaction were discussed, which will be helpful in the understanding of catalytic arylations with diaryliodonium salts.