文献类型：期刊文献

英文题名：Cerium and tin oxides anchored onto reduced graphene oxide for selective catalytic reduction of NO with NH3 at low temperatures

作者：Wang, Yanli[1];Kang, Ying[1];Ge, Meng[1];Zhang, Xiu[1];Zhan, Liang[1,2]

机构：[1]East China Univ Sci & Technol, Shanghai Key Lab Multiphase Mat Chem Engn, Key Lab Specially Funct Polymers & Related Techno, State Key Lab Chem Engn,Minist Educ, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Inst Coal Chem, CAS Key Lab Carbon Mat, Taiyuan 030001, Shanxi, Peoples R China

年份：2018

卷号：8

期号：63

起止页码：36383

外文期刊名：RSC ADVANCES

收录：;EI(收录号：20184606056543);WOS:【SCI-EXPANDED(收录号:WOS:000448663500062)】；

基金：This work was financially supported by National Science Foundation of China (No. 51472086, 51002051, 20806024) and CAS Key Laboratory of Carbon Materials (No. KLCMKFJJ1703).

语种：英文

外文关键词：Tin oxides - Selective catalytic reduction - Catalyst activity - Catalyst selectivity - Graphene - Reduction - Ammonia

摘要：A series of cerium and tin oxides anchored on reduced graphene oxide (CeO2-SnOx/rGO) catalysts are synthesized using a hydrothermal method and their catalytic activities are investigated by selective catalytic reduction (SCR) of NO with NH3 in the temperature range of 120-280 degrees C. The results indicate that the CeO2-SnOx/rGO catalyst shows high SCR activity and high selectivity to N-2 in the temperature range of 120-280 degrees C. The catalyst with a mass ratio of (Ce + Sn)/GO = 3.9 exhibits NO conversion of about 86% at 160 degrees C, above 97% NO conversion at temperatures of 200-280 degrees C and higher than 95% N-2 selectivity at 120-280 degrees C. In addition, the catalyst presents a certain SO2 resistance. It is found that the highly dispersed CeO2 nanoparticles are deposited on the surface of rGO nanosheets, because of the incorporation of Sn4+ into the lattice of CeO2. The mesoporous structures of the CeO2-SnOx/rGO catalyst provides a large specific surface area and more active sites for facilitating the adsorption of reactant species, leading to high SCR activity. More importantly, the synergistic interaction between cerium and tin oxides is responsible for the excellent SCR activity, which results in a higher ratio of Ce3+/(Ce3+ + Ce4+), higher concentrations of surface chemisorbed oxygen and oxygen vacancies, more strong acid sites and stronger acid strength on the surface of the CeSn(3.9)/rGO catalyst.