文献类型：期刊文献

英文题名：Synthesis of fluorine-containing block copolymers via ATRP 2. Synthesis and characterization of semifluorinated di- and triblock copolymers

作者：Zhang, Z.-B.[1]; Ying, S.-K.[1]; Shi, Z.-Q.[1]

机构：[1]E China Univ Sci & Technol, Lab Living Polymerizat, Shanghai 200237, Peoples R China;[2]Shanghai Inst Organo Fluorine Mat, Shanghai, Peoples R China

年份：1999

卷号：40

期号：19

起止页码：5439

外文期刊名：POLYMER

收录：;EI(收录号：1999084754987);WOS:【SCI-EXPANDED(收录号:WOS:000080803400023)】；

语种：英文

外文关键词：atom transfer radical polymerization; semifluorinated block copolymer

摘要：A series of semifluorinated fluorocarbon/hydrocarbon di- and triblock copolymers were prepared by atom transfer radical polymerization (ATRP). The mono- and difunctional macroinitiators, which were obtained from bulk ATRP of styrene, butyl acrylate and methyl acrylate, initiated solution ATRP of 2- [(perfluorononenyl)oxy]ethyl methacrylate and ethylene glycol mono-methacrylate mono-perfluorooctanoate, respectively. The formation of the block copolymer was confirmed with size exclusion chromatography and H-1 NMR spectrum. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.