文献类型：期刊文献

英文题名：STUDY OF CHEMICAL-EQUILIBRIA IN METHANOL SYNTHESIS .2. CALCULATION OF EQUILIBRIUM-CONSTANT KP

作者：LIU, H; LUO, ZC; ZHU, BC

机构：[1]E CHINA UNIV SCI & TECHNOL,DEPT CHEM ENGN,SHANGHAI 200237,PEOPLES R CHINA

年份：1994

卷号：12

期号：6

起止页码：829

外文期刊名：FUEL SCIENCE & TECHNOLOGY INTERNATIONAL

收录：;WOS:【SCI-EXPANDED(收录号:WOS:A1994NJ60600002)】；

语种：英文

摘要：Based on the experimental data of K(P) measured in this paper, the thermodynamic calculation of K(P) from K(f) and equation of state was studied and it was found that the chemical equilibrium of methanol synthesis can be described well by using Cherednichenko (1963)'s K(f, CO) and Bissett (1977)'s K(f, RS) relationship sad a modified SRK equation. Meanwhile, the equilibrium constant K(f) it methanol synthesis in literature since 1930s were appraised. It was found that the obvious deviations of K(f) values of different authors would be given because of different basic thermochemical data and the accumulations of the deviations.