文献类型：期刊文献

英文题名：Pd(II)-catalyzed and diethylzinc-mediated asymmetric umpolung allylation of aldehydes in the presence of chiral phosphine-Schiff base type ligands

作者：Jiang, Jia-Jun[1,2];Wang, De[1,2];Wang, Wen-Feng[1,2];Yuan, Zhi-Liang[1,2];Zhao, Mei-Xin[1,2];Wang, Fei-Jun[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

年份：2010

卷号：21

期号：16

起止页码：2050

外文期刊名：TETRAHEDRON-ASYMMETRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000281977500017)，CCR-EXPANDED(收录号:WOS:000281977500017)】；

基金：Financial support from the Shanghai Municipal Committee of Science and Technology (08dj1400100-2), National Basic Research Program of China (973)-2010CB833302, and the National Natural Science Foundation of China (20902019, 20872162, 20672127, 20821002, 20732008, 20772030 and 20702059) is greatly acknowledged.

语种：英文

摘要：Chiral phosphine-Schiff base type ligand L3 prepared from (R)-(-)-2-(diphenylphosphino)-1,1'-binaphthyl-2'-amine was found to be a fairly effective chiral ligand for the Pd(II)-catalyzed and diethylzinc-mediated enantioselective umpolung allylation of aldehydes to give homoallylic alcohols in good yields, moderate enantioselectivities and high syn diastereoselectivities. (C) 2010 Elsevier Ltd. All rights reserved.