文献类型：期刊文献

英文题名：A Tandem Reaction of Benzyne with Functionalized Benzylidenephthalan To Afford Phenanthro[10,1-bc]furan

作者：Hai Xiao Siyang;Wu, Xu Rui;Liu, Hui Ling;Wu, Xin Yan;Liu, Pei Nian[1]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2014

卷号：79

期号：3

起止页码：1505

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：;EI(收录号：20140817347107);WOS:【SCI-EXPANDED(收录号:WOS:000331163800072)，CCR-EXPANDED(收录号:WOS:000331163800072)】；

基金：This work was supported by the National Natural Science Foundation of China (Project Nos. 21172069, 21190033, and 21372072), the Innovation Program of the Shanghai Municipal Education Commission (Project No. 12ZZ050), the Basic Research Program of the Shanghai Committee of Science and Technology (Project No. 13NM1400802), and the Fundamental Research Funds for the Central Universities.

语种：英文

外文关键词：Aromatic compounds - Organic pollutants

摘要：A tandem reaction of benzyne with function-, alized benzylidenephthalan for the synthesis of a variety of phenanthro[10,1-bc]furans has been achieved for the first time in moderate to good yields. The reaction mechanism involves a Diels-Alder reaction and an intermolecular nucleophilic addition reaction as the key steps.