文献类型：期刊文献

中文题名：全氟萘烷的化学还原与电化学还原

英文题名：On the Chemical Reduction and Electro- reduction Behavior of Perfluorodecalin

作者：张存中[1];雷惊雷[1];蔡生民[1];杨迈之[1];田禾[2]

机构：[1]北京大学化学与分子工程学院,北京100871;[2]华东理工大学精细化工系

年份：2002

卷号：19

期号：5

起止页码：506

中文期刊名：应用化学

外文期刊名：Chinese Journal of Applied Chemistry

收录：CSTPCD;;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

基金：国家自然科学基金 (2 98770 0 3 );高等学校博士点专项科研基金;厦门大学固体表面物理化学国家重点实验室基金;中国科学院有机固体开放实验室部分资助项目

语种：中文

中文关键词：全氟萘烷;还原;电化学还原

外文关键词：perfluorodecalin,reduction,electro reduction

摘要：The chemical reduction and electro reduction behavior of perfluorodecalin have been investigated under the illumination of UV light. The IR spectra of the resulting products showed that the same functional group, acyl fluoride, could be formed in both reduction processes. The results of 19 F NMR and UV vis spectra revealed that there were other different functional groups formed in the two reduction processes. In the electro chemical reduction , conjunctive double bonds could be formed in the same and different carbon ring. In the chemical reduction, using Zn and Mg as reducing agents, aromatic structure was formed in the products.
The chemical reduction and electro reduction behavior of perfluorodecalin have been investigated under the illumination of UV light. The IR spectra of the resulting products showed that the same functional group, acyl fluoride, could be formed in both reduction processes. The results of 19 F NMR and UV vis spectra revealed that there were other different functional groups formed in the two reduction processes. In the electro chemical reduction , conjunctive double bonds could be formed in the same and different carbon ring. In the chemical reduction, using Zn and Mg as reducing agents, aromatic structure was formed in the products.