详细信息

A STUDY ON THE ULLMANN CONDENSATION REACTION OF 4-CHLORO-1,8-NAPHTHALIC ANHYDRIDE WITH N,N-DIMETHYLFORMAMIDE  ( SCI-EXPANDED收录)  

文献类型:期刊文献

英文题名:A STUDY ON THE ULLMANN CONDENSATION REACTION OF 4-CHLORO-1,8-NAPHTHALIC ANHYDRIDE WITH N,N-DIMETHYLFORMAMIDE

作者:QIAN, XH; ZHU, ZH; CHEN, KC

机构:[1]E CHINA UNIV CHEM TECHNOL,FINE CHEM RES INST,SHANGHAI 200237,PEOPLES R CHINA

年份:1992

卷号:334

期号:2

起止页码:161

外文期刊名:JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG

收录:;WOS:【SCI-EXPANDED(收录号:WOS:A1992HN67700011)】;

语种:英文

摘要:We studied the reaction kinetics, the change of copper salts catalyst and behaviour of DMF in the Ullmann condensation reaction of 4-chloro-1,8-naphthalic anhydride with DMF under the catalysis of CuSO4 by using u.v., e.s.r., n.m.r. and m.s. DMF is a good amination reagent, and its reducing effect to cupric salts accelerates the reaction.

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