文献类型：期刊文献

中文题名：卟啉锡敏化TiO_2纳米管的光催化活性和光电性能

英文题名：Photocatalytic Activity and Optoelectronic Property of Porphyrin Tin-Sensitized TiO_2 Nanotubes

作者：黄成[1];常婷[2];张越[1];康诗钊[1];李向清[1];穆劲[1]

机构：[1]上海应用技术学院化学与环境工程学院,上海201418;[2]华东理工大学化学与分子工程学院,上海200237

年份：2014

卷号：30

期号：2

起止页码：331

中文期刊名：无机化学学报

外文期刊名：Chinese Journal of Inorganic Chemistry

收录：CSTPCD;;Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000332434100015)】；北大核心:【北大核心2011】；CSCD:【CSCD2013_2014】；

基金：国家自然科学基金重点(No.20933007)资助项目

语种：中文

中文关键词：卟啉锡;敏化;二氧化钛纳米管;光催化

外文关键词：porphyrin tin; sensitization; TiO2 nanotubes; photocatalysis

摘要：制备了反-二羟基-5,10,15,10-四苯基卟啉锡敏化的TiO2纳米管,并以对硝基苯酚为模型污染物,对其在可见光照射下的光催化活性进行了研究。同时,将卟啉锡敏化的TiO2纳米粒子作为参照物,探讨了形貌对催化剂光催化活性的影响。实验结果表明,卟啉锡的引入可以明显地增强TiO2纳米管的可见光催化活性。与TiO2纳米粒子相比,卟啉锡对TiO2纳米管的敏化作用更加显著,表明催化剂的形貌在光催化过程中具有重要作用。此外,我们还考察了卟啉锡敏化的TiO2纳米管的光电化学行为,并与其光催化活性相关联。最后,对卟啉锡的敏化机理进行了初步的探讨。
TiO2 nanotubes sensitized with trans-dihydroxo[5,10,15,10-tetraphenyl porphyrin] tin（Ⅳ） （abbreviated to SnTPP） were prepared. The photocatalytic activity of SnTPP-sensitized TiO2 nanotubes were evaluated by using p-nitrophenol as a model contaminant under visible light irradiation. Meanwhile, SnTPP-sensitized TiO2 nanoparticles were selected as a reference substance to explore the effect of morphology on the photocatalytic activity of catalysts. The experimental results show that introduction of SnTPP can significantly enhance the visible light photocatalytic activity of TiO2 nanotubes. And TiO2 nanotubes show higher sensitizing effect of SnTPP than TiO2 nanoparticles, indicating that the morphology of a catalyst plays an important role in the photocatalytic process. In addition, the photoelectrochemical behavior of SnTPP-sensitized TiO2 nanotubes was examined and related with the photocatalytic activity. Finally, the sensitizing mechanism of SnTPP was discussed preliminarily.