文献类型：期刊文献

中文题名：硝酸钙对内蒙古褐煤热解和气化特性的影响

英文题名：Effects of calcium nitrate on pyrolysis and gasification behavior of lignite from Inner Mongolia

作者：彭康[1];王亦飞[1];金渭龙[1];吴超琦[1];王辅臣[1]

机构：[1]华东理工大学煤气化及能源化工教育部重点实验室,上海200237

年份：2013

卷号：41

期号：2

起止页码：144

中文期刊名：燃料化学学报

外文期刊名：Journal of Fuel Chemistry and Technology

收录：CSTPCD;;EI(收录号：20131416161945);Scopus;北大核心:【北大核心2011】；CSCD:【CSCD2013_2014】；

基金：上海市优秀学科带头人资助计划(08XD1401306)

语种：中文

中文关键词：硝酸钙;煤热解;煤气化;气相产物

外文关键词：calcium nitrate; coal pyrolysis; coal gasification; gaseous products

摘要：在小型固定床反应装置上开展了内蒙古褐煤原煤(RC)和脱灰煤(DC)以及分别负载钙盐的煤样的热解实验,并对热解所得焦样开展了焦样与水蒸气气化反应的实验研究。结果表明,硝酸钙的添加对煤的热解和气化阶段均有影响。在热解阶段,硝酸钙的存在能显著改变主要气相产物H2、CO2和CO等组分的逸出规律和累积生成量;在气化阶段,作为催化剂的碱土金属,降低了焦样的气化反应活化能,更有利于气化反应的进行。
The pyrolysis of original coal （a lignite from Inner Mongolia）, acid washing deashed coal and calcium nitrate loaded coal was investigated in a small fixed-bed reactor, and the gasification activity with steam for different chars was compared as well. The results show that both coal pyrolysis and gasification processes are affected by addition of calcium nitrate. Calcium nitrate can obviously promote the pyrolysis reaction and change the release regularity and cumulative quantity of main gaseous products （ HE, CO2 and CO） ; while the alkaline- earth metal as a catalyst can reduce the gasification activation energy and promote the char gasification with steam.