文献类型：期刊文献

英文题名：A thermally reversible photoinduced magnetic trinuclear complex [Cu₂(bpmen)₂][Mo^IV(CN)₈]?8H₂O

作者：Xu, Haitao[1];Sato, Osamu[2];Li, Zhihua[3];Ma, Jianping[3]

机构：[1]E China Univ Sci & Technol, Chem Engn Res Ctr, Sch Chem Engn, Shanghai 200092, Peoples R China;[2]Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan;[3]Shandong Normal Univ, Dept Chem, Jinan 250014, Shandong, Peoples R China

年份：2012

卷号：15

起止页码：311

外文期刊名：INORGANIC CHEMISTRY COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000300812100074)】；

基金：Financial support from the Japan Society for the Promotion of Science (JSPS) is gratefully acknowledged. This work was supported in part by China Ministry of Education within the project A200-C-1101.

语种：英文

外文关键词：Crystal structure; Trinuclear complex; Molecule-based materials; Photomagnetic property; Charge transfer

摘要：A trinuclear complex [Cu-2(II)(bpmen)(2)][Mo-IV(CN)(8)]center dot 8H(2)O was synthesized and structurally characterized, crystallized in the monoclinic system, space group Cc with cell constants a = 11.726(2) angstrom, b = 17.158(3) angstrom, c = 23.891(5) angstrom, beta = 97.96(3)degrees and Z = 4. It exhibited thermally reversible photo-responsive properties on UV light irradiation through a Mo-IV to Cu-II charge transfer, which is potential interest for the molecular storage of information as a multifunctional molecule-based material. (C) 2011 Elsevier B.V. All rights reserved.