文献类型：期刊文献

中文题名：芳基乙炔聚合物固化反应动力学和结构表征

英文题名：Curing Kinetics and Structure Characterization of Arylacetylene Polymer

作者：丁学文[1];齐会民[1];庄元其[1];王俊[1];徐柏华[1];焦扬声[1]

机构：[1]华东理工大学功能复合材料研究室,上海200237

年份：2001

卷号：27

期号：2

起止页码：161

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;Scopus;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：芳基乙炔聚合物;多烯结构;固化反应动力学;端快基聚合物;二乙炔基苯;碳/碳复合材料

外文关键词：arylacetylene polymer; polyene structure; curing kinetics; acetylene terminated resin; diethynylbenzene

摘要：应用 DSC和 FTIR分析技术 ,研究了芳基乙炔聚合物的固化反应动力学和固化反应过程中的结构变化。结果表明 :芳基乙炔聚合物固化过程中主要形成顺式共轭多烯结构。芳基乙炔聚合物的固化反应活化能为 1 0 8.6～ 1 1 9.7k J/mol,单体结构对聚合物的固化反应速率有明显影响 ,聚 1 ,4-二乙炔基苯 ( p- DEB)的固化反应速率比聚 1 ,3-二乙炔基苯 ( m- DEB)
DSC and FTIR were used to characterize the curing kinetics and the structure changes of polyarylacetylene. The results indicate that cis conjugated polyene structures are formed predominantly during the curing of arylacetylene polymer. Monomer structure has a significant influence on the curing reaction rate of the polymer. Poly ( p DEB) has a lower maximum reaction temperature and curing reaction activation energy than that of poly ( m DEB) because of their different structures. This indicates that Poly ( p DEB) has a higher curing reaction rate than that of poly ( m DEB). The curing reaction activation energies of the three kinds of polymers are in the range of 108.6～119.7kJ/mol.