文献类型：期刊文献

英文题名：The coupling reactions of aryl halides and phenols catalyzed by palladium and MOP-type ligands

作者：Zhang, Yi[1];Ni, Gang[2];Li, Chengjun[1];Xu, Sheng[2];Zhang, Zhaoguo[1];Xiaomin, Xie[1]

机构：[1]Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

年份：2015

卷号：71

期号：30

起止页码：4927

外文期刊名：TETRAHEDRON

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000357224200004)，CCR-EXPANDED(收录号:WOS:000357224200004)】；

基金：We thank the National Natural Science Foundation of China for financial support (Grant No. 21272156 and u1362111).

语种：英文

外文关键词：Palladium; Coupling reaction; Diaryl ether; Phosphines; o-Xylene

摘要：Palladium-catalyzed coupling reactions of aryl halides and phenols are described employing the bulky and electron-rich MOP-type ligands. When K3PO4 was used as base and toluene as solvent, the catalyst system exhibited high efficiency for the coupling reaction of the activated aryl halides. When NaH was used as base and o-xylene as solvent, unactivated aryl halides can be used as substrates. (C) 2015 Elsevier Ltd. All rights reserved.