沈本贤 收藏
( 任职于 化工学院)
【社会兼职】 中国无机盐工业协会副会长，上海市发明协会会长，中国化工学会化肥专业委员会副主任，上海市化学化工学会副理事长。 【研究方向】 课题组立足于盐湖资源综合利用和工业大宗废弃物资源化等国家重大战略需求，服务于行业与区域经济建设，针对无机矿产资源开发需求的重大关键、基础、共性技术难题，通过自主研发、产学研结合、消化吸收在创新和国际交流合作等多种途径，进行系统化的工程研究。面向钾、镁、锂、硼等重要的无机矿产资源开发、高盐废水资源利用、大宗工业废弃物资源化，设置了三个研究方向： （1）复杂物质体系先进分离技术 系统研... 详细>>
被引量：4,417H指数：28SCI-EXPANDED： 159 EI： 249 北大核心： 255 CSCD： 256
- Kinetics of Acetylene Hydrochlorination over Bimetallic Au-Cu/C Catalyst被引量：135收藏
- 作者：Wang, Shengjie Shen, Benxian Song, Qinglei
- 机构：E China Univ Sci & Technol
- 来源：CATALYSIS LETTERS 2010
- 关键词：Kinetics Mechanism Acetylene hydrochlorination Bimetallic Au-Cu catalyst
- 质疑
- Characterization and Comparison of Nitrogen Compounds in Hydrotreated and Untreated Shale Oil by Electrospray Ionization (ESI) Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS)被引量：75收藏
- 作者：Chen, Xiaobo Shen, Benxian Sun, Jinpeng Wang, Chengxiu Shan, Honghong Yang, Chaohe Li, Chunyi
- 机构：E China Univ Sci & Technol;China Univ Petr
- 来源：ENERGY & FUELS 2012
- 关键词：Mass spectrometry - Cyclotrons - Shale oil - Fourier transforms - Electron cyclotron resonance - Fourier transform infrared spectroscopy - Nitrogen compounds
- 质疑
- Tuning 1-hexene/n-hexane adsorption on MOF-74 via constructing Co-Mg bimetallic frameworks被引量：72收藏
- 作者：Sun, Hui Ren, Danni Kong, Ruiqi Wang, Dan Jiang, Hao Tan, Jialun Wu, Di Chen, Shengwei Shen, Benxian
- 机构：East China Univ Sci & Technol;East China Univ Sci & Technol;Washington State Univ;Washington State Univ;Washington State Univ
- 来源：MICROPOROUS AND MESOPOROUS MATERIALS 2019
- 关键词：1-Hexene/n-hexane separation Adsorption Selectivity MOF-74 Bimetallic
- 质疑
- Palladium-Based Catalysts for the Hydrochlorination of Acetylene: Reasons for Deactivation and Its Regeneration被引量：68收藏
- 作者：Song, Q. L. Wang, S. J. Shen, B. X. Zhao, J. G.
- 机构：E China Univ Sci & Technol
- 来源：PETROLEUM SCIENCE AND TECHNOLOGY 2010
- 关键词：deactivation hydrochlorination palladium chloride regeneration
- 质疑
- Enhancing the production of biofuels from cottonseed oil by fixed-fluidized bed catalytic cracking被引量：65收藏
- 作者：Li, Hong Shen, Benxian Kabalu, J. C. Nchare, Mominou
- 机构：E China Univ Sci & Technol
- 来源：RENEWABLE ENERGY 2009
- 关键词：Catalytic cracking Fixed-fluidized reactor Response surface methodology
- 质疑
- Ion-exchange modified zeolites X for selective adsorption desulfurization from Claus tail gas: Experimental and computational investigations被引量：64收藏
- 作者：Chen, Xi Shen, Benxian Sun, Hui Zhan, Guoxiong
- 机构：East China Univ Sci & Technol
- 来源：MICROPOROUS AND MESOPOROUS MATERIALS 2018
- 关键词：Silver compounds - Ion exchange - Metal ions - Metals - Zeolites - Adsorption
- 质疑
- 铁基助熔剂对皖北刘桥二矿煤的灰熔融特性影响研究被引量：63收藏
- 作者：李继炳 沈本贤 李寒旭 赵基钢 王基铭
- 机构：华东理工大学化学工程联合国家重点实验室;中国石油化工股份有限公司安庆分公司;安徽理工大学化学工程学院
- 来源：《燃料化学学报》 2009
- 关键词：煤 灰熔融特性 铁基助熔剂
- 摘要：研究了铁基助熔剂对皖北刘桥二矿煤(AQ)灰熔融特征的影响,并对AQ煤灰在添加铁基助熔剂前后不同热处理温度下的矿物组成进行了XRD和红外光谱分析。结果表明,导致AQ煤灰熔点高的主要原因是1000℃以上形成的莫来石引起的;加...
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- Unveiling the Quantitative Relationships between Electron Distribution and Steric Hindrance of Organic Amines and Their Reaction Rates with Carbonyl Sulfur: A Theoretical Calculation Investigation被引量：56收藏
- 作者：Liu, Chuanlei Chen, Yuxiang Guo, Guanchu Zhao, Qiyue Jiang, Hao Wang, Hao Gao, Weikang Yang, Fengjing Shen, Ben-Xian Sun, Hui
- 机构： School of Chemical Engineering; International Joint Research Center of Green Energy Chemical Engineering; Ministry Key Laboratory of Oil and Gas Fine Chemicals
- 来源：Journal of Physical Chemistry A 2024
- 关键词：Amines - Forecasting - Gas absorption - Ionization of gases - Ionization potential - Molecules - Petroleum prospecting - Phosphorus compounds - Solvents - Sulfur - Sulfur compounds
- 质疑
- 蜡晶形态结构对原油降凝的影响被引量：56收藏
- 作者：张红 沈本贤
- 机构：华东理工大学石油加工研究所
- 来源：《石油学报（石油加工）》 2006
- 关键词：原油 蜡晶结构 降凝机理
- 摘要：采用偏光显微镜观察了不同条件下蜡晶的形态变化,对蜡结晶过程中的结构、分布状态和生长规律进行了深入的研究,采用气相色谱分析了用52#、62#、80#蜡配制的模拟油中蜡的碳数分布,考察了凝点与蜡含量之间的变化规律,以及沥青质...
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- Metal-Modified Cu-BTC Acid for Highly Enhanced Adsorption of Organosulfur Species被引量：53收藏
- 作者：Sun, Hui Han, Xiao Liu, Kefeng Shen, Benxian Liu, Jichang Wu, Di Shi, Xiaoyu
- 机构：East China Univ Sci & Technol;Washington State Univ;Washington State Univ;Washington State Univ
- 来源：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 2017
- 关键词：Fourier transform infrared spectroscopy - Scanning electron microscopy - Organometallics - Sulfur compounds - Adsorption - X ray diffraction - X ray photoelectron spectroscopy - Copper compounds - Porous materials
- 质疑
- Molecular-Level-Process Model with Feedback of the Heat Effects on a Complex Reaction Network in a Fluidized Catalytic Cracking Process被引量：49收藏
- 作者：Liu, Jichang Chen, Hua Pi, Zhipeng Liu, Yifeng Sun, Hui Shen, Benxian
- 机构：East China Univ Sci & Technol
- 来源：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 2017
- 关键词：Fluidization - Fluid catalytic cracking - Kinetic parameters - Complex networks - Cracks - Reaction kinetics - Feedback - Kinetic theory - Sols
- 质疑
- Successively separating C3H6 and C2H4 from C2H4/C2H6/C3H6/C3H8 mixture in tandem fixed beds involving two zeolites LTA well-regulated via low transition-metal doping被引量：48收藏
- 作者：Chen, Yu Jiang, Hao Peng, Qilong Fang, Diyi Liu, Chuanlei Wu, Kongguo Chen, Yuxiang Gao, Weikang Wang, Hao Guo, Guanchu Yang, Fengjing Li, Peicheng Shen, Benxian Zhang, Feng Wu, Di Sun, Hui
- 机构： School of Chemical Engineering; International Joint Research Center of Green Energy Chemical Engineering; SINOPEC Research Institute of Petroleum Processing Co.; Alexandra Navrotsky Institute for Experimental Thermodynamics; The Gene and Linda Voiland School of Chemical Engineering and Bioengineering
- 来源：Chemical Engineering Journal 2023
- 关键词：Adsorption - Binary mixtures - Cadmium compounds - Nickel compounds - Olefins - Silver compounds - Transition metals - Zeolites
- 质疑
- Building and Application of Delayed Coking Structure-Oriented Lumping Model被引量：45收藏
- 作者：Tian, Lida Shen, Benxian Liu, Jichang
- 机构：E China Univ Chem Technol
- 来源：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 2012
- 关键词：Liquids - Sols
- 质疑
- Biofuel potential production from cottonseed oil: A comparison of non-catalytic and catalytic pyrolysis on fixed-fluidized bed reactor被引量：42收藏
- 作者：Li, Hong Yu, Penghao Shen, Benxian
- 机构：E China Univ Sci & Technol
- 来源：FUEL PROCESSING TECHNOLOGY 2009
- 关键词：Cottonseed oil Catalytic cracking Thermal cracking
- 质疑
- 乙炔氢氯化反应高分散载金催化剂的制备及催化性能被引量：40收藏
- 作者：王声洁 沈本贤 肖卫国 宋庆雷
- 机构：华东理工大学化学工程联合国家重点实验室;天津大沽化工股份有限公司
- 来源：《石油学报（石油加工）》 2010
- 关键词：Au(en)2Cl3 乙炔 氢氯化 金
- 摘要：采用Au(en)2Cl3作前驱体,制备了用于乙炔氢氯化反应的载Au催化剂,并采用N2-吸附、XRD、TEM进行了表征。在常压固定床反应器中考察了Au的价态、载体、Au负载量、碱金属助剂对Au催化剂活性的影响。结果表明,催...
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- An Au-Cu bimetal catalyst for acetylene hydrochlorination with renewable γ-Al2O3 as the support被引量：38收藏
- 作者：Zhao, Jigang Zeng, Junjian Cheng, Xiaoguang Wang, Lei Yang, Henghua Shen, Benxian
- 机构：E China Univ Sci & Technol;TianjinDagu Chem Co Ltd
- 来源：RSC ADVANCES 2015
- 关键词：Catalyst supports - Copper compounds - Deposition - Potassium hydroxide - Acetylene - Binary alloys - Carbon dioxide - Aluminum oxide - Temperature programmed desorption - Thermogravimetric analysis - Catalyst activity - Fourier transform infrared spectroscopy - Scanning electron microscopy - X ray photoelectron spectroscopy - Chemical activation - Alumina - Chemical reactors - Lighting - X ray diffraction
- 质疑
- A Delayed Coking Model Built Using the Structure-Oriented Lumping Method被引量：36收藏
- 作者：Tian, Lida Shen, Benxian Liu, Jichang
- 机构：E China Univ Sci & Technol
- 来源：ENERGY & FUELS 2012
- 关键词：Coking
- 质疑
- Ion-Exchanged Zeolites Y for Selective Adsorption of Methyl Mercaptan from Natural Gas: Experimental Performance Evaluation and Computational Mechanism Explorations被引量：34收藏
- 作者：Chen, Xi Shen, Ben-xian Sun, Hui Zhan, Guo-xiong
- 机构：East China Univ Sci & Technol
- 来源：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 2017
- 关键词：Computation theory - Natural gas - Density functional theory - X ray photoelectron spectroscopy - Carbon dioxide - X ray diffraction - Chemical analysis - Chemical bonds - Fourier transform infrared spectroscopy - Ion exchange - Ions
- 质疑
- Remixing Control for Divided-Wall Columns被引量：33收藏
- 作者：Ling, Hao Cai, Zhi Wu, Hao Wang, Jun Shen, Benxian
- 机构：E China Univ Sci & Technol;Sinopec Jiujiang Co
- 来源：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 2011
- 关键词：Energy utilization - Mixtures - Energy conservation - Closed loop control systems
- 质疑
- Building a Kinetic Model for Steam Cracking by the Method of Structure-Oriented Lumping被引量：33收藏
- 作者：Tian, Lida Wang, Jiming Shen, Benxian Liu, Jichang
- 机构：E China Univ Sci & Technol
- 来源：ENERGY & FUELS 2010
- 关键词：Kinetic theory - Ethylene - Rate constants - Runge Kutta methods - Cracks - Differential equations - Ethylene glycol - Kinetic parameters
- 质疑
- Chemical Liquid Deposition Modified ZSM-5 Zeolite for Adsorption Removal of Dimethyl Disulfide被引量：32收藏
- 作者：Zhao, Ya-wei Shen, Ben-xian Sun, Hui
- 机构：E China Univ Sci & Technol
- 来源：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 2016
- 关键词：Sulfur compounds - Pore size - X ray photoelectron spectroscopy - Adsorbents - Temperature programmed desorption - Zeolites - Adsorption - Calcination
- 质疑
- ^1H—NMR和IR对道路沥青老化过程的研究被引量：32收藏
- 作者：水恒福 沈本贤 高晋生 周华
- 机构：华东理工大学石油加工研究所;马鞍山职业教育中心
- 来源：《华东理工大学学报（自然科学版）》 1998
- 关键词：核磁共振 红外光谱 老化 机理 道路沥青
- 摘要：研究了两种不同结构道路沥青Ｓｈｅｌ７０和ＰＡ１００的老化过程。发现沥青的组成和结构对其老化性能有较大影响：具有较长烷基侧链的道路沥青，在一定的温度下，烷基侧链易于断裂形成自由基而引发氧化反应；沥青各组分结构上的不连续性导...
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- Au-K/C催化剂用于乙炔氢氯化反应制氯乙烯的催化性能被引量：31收藏
- 作者：王声洁 沈本贤 肖卫国 宋庆雷 赵基钢
- 机构：华东理工大学化学工程联合国家重点实验室;天津大沽化工股份有限公司
- 来源：《华东理工大学学报（自然科学版）》 2010
- 关键词：Au—K/C催化剂 乙炔 氢氯化 氯乙烯
- 摘要：采用过量溶液浸渍法制备了用于乙炔氢氯化反应的Au-K/C催化剂,并对其进行了X射线衍射(XRD)、扫描电子显微镜(SEM)和BET表征。分析结果表明,Au-K/C催化剂活性组分在载体表面高度分散。在常压固定床反应器中,通...
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- 甲酸络合萃取脱除焦化蜡油中碱性氮化合物的研究被引量：30收藏
- 作者：凌昊 沈本贤 高玉延 陈新忠
- 机构：华东理工大学化工学院
- 来源：《石油炼制与化工》 2003
- 关键词：焦化 蜡油 碱性氮化合物 催化裂化 石油产品 甲酸 络合萃取
- 摘要：为了降低焦化蜡油(CGO)中碱性氮化合物含量,防止碱性氮化合物毒害催化裂化和催化重整催化剂,在实验室条件下考察了不同萃取时间、温度、剂油体积比和甲酸含量等工艺条件对甲酸络合萃取脱除CGO中碱性氮化合物的影响。试验结果表明...
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- 乙炔氢氯化PdCl_2/C催化剂失活原因分析被引量：29收藏
- 作者：王声洁 沈本贤 赵基钢 刘纪昌
- 机构：化学工程联合国家重点实验室华东理工大学
- 来源：《石油化工》 2009
- 关键词：乙炔 氯乙烯 氢氯化 氯化钯 活性炭 氯化钾 催化剂失活
- 摘要：采用浸渍法制备了PdCl2／C催化剂，考察了PdCl2／C催化剂用于乙炔氢氯化反应制取氯乙烯的催化性能，并用微结构分析仪、扫描电子显微镜、热重分析和电感耦合等离子体发射光谱等表征方法对PdCl2／C催化剂的失活原因进行了...
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- Study on the effects of acetylene on an Au-Cu/C catalyst for acetylene hydrochlorination using Monte Carlo and DFT methods被引量：29收藏
- 作者：Ma, Junmei Wang, Shengjie Shen, Benxian
- 机构：Shanghai Univ Finance & Econ;E China Univ Sci & Technol
- 来源：REACTION KINETICS MECHANISMS AND CATALYSIS 2013
- 关键词：Acetylene hydrochlorination Au-Cu/C catalyst Monte Carlo DFT method
- 质疑
- 道路沥青老化动力学研究被引量：28收藏
- 作者：水恒福 沈本贤 高晋生
- 机构：华东理工大学石油加工研究所
- 来源：《华东理工大学学报（自然科学版）》 1998
- 关键词：组成 结构 耐老化性能 动力学 道路沥青
- 摘要：研究了两种道路沥青老化动力学，计算得到有关动力学参数，揭示了沥青组成结构与其老化性能之间的关系。结果表明道路沥青老化属于一级动力学反应。较低芳香度和较长烷基侧链的沥青，在受热条件下其烷基侧链易于断裂而形成自由基，引发了氧...
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- Adsorption and Its Mechanism of CS2 on Ion-Exchanged Zeolites Y被引量：28收藏
- 作者：Chen, Xi Shen, Ben-xian Sun, Hui Zhan, Guo-xiong Huo, Zhen-zhen
- 机构：East China Univ Sci & Technol
- 来源：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 2017
- 关键词：Chemical analysis - Computation theory - Zeolites - Metals - Silver compounds - Metal ions - Carbon disulfide - Ion exchange - X ray photoelectron spectroscopy - Density functional theory
- 质疑
- N-Paraffins adsorption with 5A zeolites: The effect of binder on adsorption equilibria被引量：27收藏
- 作者：Sun, Hui Shen, Benxian Liu, Jichang
- 机构：E China Univ Sci & Technol
- 来源：SEPARATION AND PURIFICATION TECHNOLOGY 2008
- 关键词：Adsorption equilibria n-Paraffins 5A zeolite Binder
- 质疑
- Novel Solvent Deasphalting Process by Vacuum Residue Blending with Coal Tar被引量：27收藏
- 作者：Long, Jian Shen, Benxian Ling, Hao Zhao, Jigang Lu, Juncai
- 机构：E China Univ Sci & Technol
- 来源：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 2011
- 关键词：Blending - Coal
- 质疑
