成果/Result
- A highly efficient catalytic system for cross-coupling of aryl chlorides and bromides with malononitrile anion by palladium carbene complexes被引量：47收藏
- 作者：Gao, CW Tao, XC Qian, YL Huang, JL
- 机构：E China Univ Sci & Technol
- 来源：CHEMICAL COMMUNICATIONS 2003
- A simple and highly efficient catalytic system for Suzuki cross-coupling using ligandless palladium chloride被引量：35收藏
- 作者：Tao, XC Zhao, YY Shen, D
- 机构：E China Univ Sci & Technol;E China Univ Sci & Technol
- 来源：SYNLETT 2004
- 关键词：ligandless palladium chloride Suzuki cross-coupling aryl bromide arylboronic acid
- Palladium-catalyzed hydroformylation of terminal arylacetylenes with glyoxylic acid被引量：29收藏
- 作者：Liu, Yang Cai, Liangzhen Xu, Sheng Pu, Weiwen Tao, Xiaochun
- 机构：East China Univ Sci & Technol
- 来源：CHEMICAL COMMUNICATIONS 2018
- The carbon material functionalized with NH2+ and SO3H groups catalyzed esterification with high activity and selectivity被引量：24收藏
- 作者：Zhan, Shaoqi Tao, Xiaochun Cai, Liangzhen Liu, Xiaohui Liu, Taoping
- 机构：E China Univ Sci & Technol;Suzhou Eleco Chem Ind Co Ltd
- 来源：GREEN CHEMISTRY 2014
- Effects of solvent and base on the palladium-catalyzed amination: PdCl2(Ph3P)2/Ph3P-catalyzed selective arylation of primary anilines with aryl bromides被引量：21收藏
- 作者：Cai, Liangzhen Qian, Xuanying Song, Wenjing Liu, Taoping Tao, Xiaochun Li, Wanfang Xie, Xiaomin
- 机构：E China Univ Sci & Technol;Shanghai Jiao Tong Univ
- 来源：TETRAHEDRON 2014
- 关键词：Palladium Amination Triphenylphosphine Diarylation Monoarylation
- A convenient and efficient palladium-catalyzed system for cross-coupling of aryl bromides with active methylene compounds被引量：14收藏
- 作者：Gao, CW Tao, XC Qian, YL Huang, JL
- 机构：E China Univ Sci & Technol
- 来源：SYNLETT 2003
- 关键词：palladium catalysis cross-coupling arylmalononitrile arylcyanoacetate aryl bromide
- NiCl2?6H2O-catalyzed homocoupling of arylboronic acids被引量：14收藏
- 作者：Liu Guyu Du Qiaoling Xie Junjie Zhang Kaili Tao Xiaochun
- 机构：E China Univ Sci & Technol
- 来源：CHINESE JOURNAL OF CATALYSIS 2006
- 关键词：nickel chloride arylboronic acid homocoupling pyridine
- 三芳胺合成的研究进展被引量：12收藏
- 作者：刘涛平 孙杰 李瑞 陶晓春
- 机构：华东理工大学化学与分子工程学院;镇江市海通化工有限公司
- 来源：《有机化学》 2011
- 关键词：三芳胺 研究进展 合成方法 钯催化 铜催化
- 摘要：三芳胺化合物的合成方法主要有3种:(1)非金属催化的胺化反应;(2)铜催化的Ullmann反应,包括使用过量铜粉为催化剂的传统的Ullmann反应、使用相转移催化剂的Ullmann反应以及使用配体的post-Ullman...
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- Homocoupling of aryl bromides catalyzed by nickel chloride in pyridine被引量：11收藏
- 作者：Tao Xiao-Chun Zhou Wei Zhang Yue-Ping Dai Chun-Ya Shen Dong Huang Mei
- 机构：E China Univ Sci & Technol;E China Univ Sci & Technol
- 来源：CHINESE JOURNAL OF CHEMISTRY 2006
- 关键词：nickel chloride homocoupling aryl bromide pyridine zinc
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- The reaction of ketones with benzaldehyde catalyzed by TiCl4?2THF被引量：10收藏
- 作者：Tao, XC Liu, RZ Meng, QH Zhao, YY Zhou, YB Huang, JL
- 机构：E China Univ Sci & Technol
- 来源：JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 2005
- 关键词：TiCl4 center dot 2THF catalysis ketones benzaldehyde polysubstituted cyclopentenone
- Acetylation of N-heteroaryl bromides via PdCl2/(o-tolyl)3P catalyzed Heck reactions被引量：10收藏
- 作者：He, Tianxiong Tao, Xiaochun Wu, Xinyan Cai, Lisheng Pike, Victor W.
- 机构：E China Univ Sci & Technol;NIMH
- 来源：SYNTHESIS-STUTTGART 2008
- 关键词：acetylation butyl vinyl ether isopropanol N-heteroaryl bromides
- SO3H and NH2+ functional carbon-based solid acid catalyzed transesterification and biodiesel production被引量：10收藏
- 作者：Cai, Liangzhen Meng, Decai Zhan, Shaoqi Yang, Xiaoxia Liu, Taoping Pu, Huiming Tao, Xiaochun
- 机构：E China Univ Sci & Technol;Suzhou Eleco Chem Ind CO Ltd
- 来源：RSC ADVANCES 2015
- 关键词：Carbon - Esters - Catalysts - Biodiesel
- Cross-coupling of aryl iodides with malononitrile catalyzed by palladium N-heterocyclic carbene complex system被引量：8收藏
- 作者：Gao, CW Tao, XC Liu, TP Huang, JL Qian, YL
- 机构：E China Univ Sci & Technol
- 来源：CHINESE JOURNAL OF CHEMISTRY 2002
- 关键词：palladium complex N-heterocyclic carbene imidazolium salt cross-coupling arylmalononitrile
- PdCl2(Ph3P)2/Salicylaldimine Catalyzed Diarylation of Anilines with Unactivated Aryl Chlorides被引量：7收藏
- 作者：Tao, Xiaochun Li, Lei Zhou, Yu Qian, Xuanying Zhao, Min Cai, Liangzhen Xie, Xiaomin
- 机构：East China Univ Sci & Technol;Shanghai Jiao Tong Univ
- 来源：CHINESE JOURNAL OF CHEMISTRY 2017
- 关键词：palladium diarylation aryl chloride triphenylphosphine salicyaldimine
- Application of Suzuki cross-coupling reaction catalyzed by ligandless palladium chloride in the synthesis of liquid crystals被引量：6收藏
- 作者：Huang, Mei Cheng, Jianhua Tao, Xiaochun Wei, Mingwang Shen, Dong
- 机构：E China Univ Sci & Technol;E China Univ Sci & Technol
- 来源：SYNTHETIC COMMUNICATIONS 2007
- 关键词：ligandless palladium catalysis trans-cyclohexyl biphenyl liquid crystals Suzuki cross-coupling
- 2,2,6,6-Tetramethylpiperidinium triflate (TMPT): a highly selective and self-separated catalyst for esterification被引量：5收藏
- 作者：Gao, Lan Liu, Taoping Tao, Xiaochun Huang, Yongmin
- 机构：East China Univ Sci & Technol;Suzhou Eleco Chem Ind Co Ltd
- 来源：TETRAHEDRON LETTERS 2016
- 关键词：Alkyl piperidinium sulfonates Esterification Selectivity Steric hindrance Self-separation
- Synthesis of 2,2′-bipyridine through catalytic coupling reaction of α-bromopyridine using nickel complex被引量：5收藏
- 作者：Qian, YL Wang, C Tao, XC Huang, JL
- 机构：E China Univ Sci & Technol
- 来源：CHINESE JOURNAL OF ORGANIC CHEMISTRY 2003
- 关键词：2-bromopyridine bipyridine catalytic coupling reaction
- Oxidation of Alcohols under Mild Conditions Using Oxone/CaCl2/TEMPO被引量：5收藏
- 作者：Tao, Xiaochun Cao, Xiongjie Yu, Wei Zhang, Juntao
- 机构：E China Univ Sci & Technol;SH Icon Inc
- 来源：CHINESE JOURNAL OF ORGANIC CHEMISTRY 2010
- 关键词：oxone alcohol calcium chloride TEMPO oxidation
- Triphenylphosphine as a Ligand for the Pd-Catalyzed Amination of Unactivated Aryl Chlorides with Anilines Promoted by Salicylaldimine被引量：5收藏
- 作者：Liu, Tao-Ping Cheng, Qiang Song, Wen-Jing Cai, Liang-Zhen Tao, Xiao-Chun
- 机构：E China Univ Sci & Technol
- 来源：SYNLETT 2012
- 关键词：amination reaction aryl chloride salicylaldimine diarylamine triphenylphosphine
- Selective oligomerization of nitriles having α-hydrogen catalyzed by alkali被引量：5收藏
- 作者：Tao, Xiaochun Liu, Taoping Tao, Hui Liu, Ruzhang Qian, Yanlong
- 机构：E China Univ Sci & Technol
- 来源：JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 2003
- 关键词：nitrites oligomerization 4-aminopyrimidine alkali catalysis
- Inhibition of homo-coupling of arylboronic acids in ligand free Pd(II)-catalyzed Suzuki reaction被引量：5收藏
- 作者：Tao, Xiao-Chun Zhang, Yue-Ping He, Tia-Xiong Shen, Dong
- 机构：E China Univ Sci & Technol;E China Univ Sci & Technol
- 来源：CHINESE JOURNAL OF CHEMISTRY 2007
- 关键词：homo-coupling cross-coupling isopropanol aryl bromide arylboronic acid
- Substituent effect on oligomerization of isoprene catalyzed by ring-substituted (RCp)2TiCl2/i-C3H7MgCl system被引量：5收藏
- 作者：Tao, XC Qian, F Yong, L Qian, YL
- 机构：E China Univ Sci & Technol
- 来源：JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 2000
- 关键词：substituent effect oligomerization of isoprene catalysis ring-substituted titanocene
- 一锅法Kumada偶联反应合成烷基吡啶化合物被引量：4收藏
- 作者：刘涛平 谢俊杰 李彬 蔡良珍 陶晓春
- 机构：华东理工大学化学与分子工程学院
- 来源：《有机化学》 2011
- 关键词：Kumada偶联反应 溴代吡啶 镍催化 一锅法
- 摘要：以溴代吡啶为原料,用简单结构的镍化合物(Py_4NiCl_2)作为催化剂,经过一锅法Kumada偶联反应合成一系列甲基、烯丙基或苄基取代的吡啶化合物,收率在中等以上.
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- Organotitanium chemistry: substituent effects on the dimerization of isoprene catalyzed by alkenyl-substituted cyclopentadienyl titanium complexes被引量：3收藏
- 作者：Yong, Li Tao, Xiaochun Qian, Fang Qian, Yanlong
- 机构：E China Univ Sci & Technol
- 来源：JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 2002
- 关键词：oligomerization of isoprene alkenyl-substituted titanocene substituent effect catalytic activity selectivity
- Copper(I) Iodide Catalyzed Cyanation of N-Heteroaryl Bromides Using Potassium Hexacyanoferrate(II)被引量：2收藏
- 作者：Cai Liangzhen Liu Bin Dong Yuhu Du Guangyan Tao Xiaochun
- 机构：E China Univ Sci & Technol
- 来源：ACTA CHIMICA SINICA 2009
- 关键词：potassium hexacyanoferrate(II) cyanation N-isopropylimidazole N,N '-dimethylethylenediamine N-heteroaryl nitrite
- Selective cyclotrimerization of acetonitrile catalyzed by sodium-based alkali被引量：2收藏
- 作者：Tao, XC Tao, H Liu, TP Qian, YL
- 机构：E China Univ Sci & Technol
- 来源：CHINESE JOURNAL OF CATALYSIS 2002
- 关键词：acetonitrile cyclotrimerization 4-aniino-2,6-dimethylpyrimidine sodium-based alkali
- The application of vinylidene ruthenium complex intermediates in organic synthesis被引量：2收藏
- 作者：Jin, JT Tao, XC Qian, YL
- 机构：E China Univ Sci & Technol
- 来源：CHINESE JOURNAL OF ORGANIC CHEMISTRY 2000
- 关键词：ruthenium complexes vinylidene nucleophilic reaction organic synthesis
- Palladium-catalyzed Coupling between Aryl Halides and Trimethylsilylacetylene Assisted by Dimethylaminotrimethyltin被引量：2收藏
- 作者：Cai Liangzhen Yang Dujuan Sun Zhonghua Tao Xiaochun Cai Lisheng Pike, Victor W.
- 机构：E China Univ Sci & Technol;NIMH
- 来源：CHINESE JOURNAL OF CHEMISTRY 2011
- 关键词：palladium catalysis trimethylsilylacetylene aryl halide dimethylaminotrimethyltin Sonogashira coupling
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- 以氯代芳烃为底物的Heck反应研究最新进展被引量：2收藏
- 作者：王静 许胜 陶晓春
- 机构：兰州石化职业技术学院石油化工系;华东理工大学化学与分子工程学院
- 来源：《有机化学》 2008
- 关键词：Heck反应 催化 氯代芳烃 进展
- 摘要：综述了近几年以氯代芳烃作为底物的Heck反应研究进展,对提高催化氯代芳烃活性的方法和催化体系的组成、结构对催化活性的影响等方面进行了介绍和评价.
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- Palladium-catalyzed Substitution of Ketone or Aldehyde Bearing Aryl Triflates by Amines or Amides被引量：1收藏
- 作者：Tao Xiaochun Dai Chunya Cao Xiongjie Cai Lisheng Pike, Victor W.
- 机构：E China Univ Sci & Technol;NIMH
- 来源：CHINESE JOURNAL OF CHEMISTRY 2009
- 关键词：aryl triflate substitution amine amide palladium phosphine ligand
